My wife isn't forthcoming about too many specifics. I know about how she lost her virginity, but I don't know with whom she learned to give blowjobs, other than her saying she decided she'd better try because the guy was willing to go down on her. Turned out she liked it.
The one story I did hear was the first time she orgasmed during sex. She'd get close, but never could get over the top. One time when she was getting really close, her then-boyfriend grabbed her hair and pulled. It shocked and surprised her so much that she came instantly, and hard. The trick apparently hasn't worked since, but it did open the door for her to be able to orgasm during sex (though not always easily).
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